Perodic Table Information

For each compound, and where possible, a formal oxidation number for each element is given, but the usefulness of this number is limited, especially so for p-block elements in particular. Based upon that oxidation number, an electronic configuration is also given but note that for more exotic compounds you should view this as a guide only.

Element	%	Formal oxidation state	Formal electronic configuration
Br	86.25	-1	[Ar].3d¹⁰.4s².4p⁶
V	13.75	4	[Ar].3d¹

Synthesis

Not available

Solid state structure

Geometry of vanadium: 4 coordinate: tetrahedral
Prototypical structure:

Crystal structure of vanadium (IV) bromide

Isotope pattern

What follows is the calculated isotope pattern for the VBr₄ unit with the most intense ion set to 100%.

Formula: V₁Br₄

mass %366 0.0 
367 17.6 _________
368 0.2 
369 68.5 __________________________________
370 0.3 
371 100.0 __________________________________________________
372 0.2 
373 64.9 ________________________________
374 0.0 
375 15.8 ________

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References

The data on these compounds pages are assembled and adapted from the primary literature and several other sources including the following.

R.T. Sanderson in Chemical Periodicity, Reinhold, New York, USA, 1960.
N.N. Greenwood and A. Earnshaw in Chemistry of the Elements, 2nd edition, Butterworth, UK, 1997.
F.A. Cotton, G. Wilkinson, C.A. Murillo, and M. Bochmann, in Advanced Inorganic Chemistry, John Wiley & Sons, 1999.
A.F. Trotman-Dickenson, (ed.) in Comprehensive Inorganic Chemistry, Pergamon, Oxford, UK, 1973.
R.W.G. Wyckoff, in Crystal Structures, volume 1, Interscience, John Wiley & Sons, 1963.
A.R.West in Basic solid state chemistry Chemistry, John Wiley & Sons, 1999.
A.F. Wells in Structural inorganic chemistry, 4th edition, Oxford, UK, 1975.
J.D.H. Donnay, (ed.) in Crystal data determinative tables, ACA monograph number 5, American Crystallographic Association, USA, 1963.
D.R. Lide, (ed.) in Chemical Rubber Company handbook of chemistry and physics, CRC Press, Boca Raton, Florida, USA, 77th edition, 1996.
J.W. Mellor in A comprehensive treatise on inorganic and theoretical chemistry, volumes 1-16, Longmans, London, UK, 1922-1937.
J.E. Macintyre (ed.) in Dictionary of inorganic compounds, volumes 1-3, Chapman & Hall, London, UK, 1992.