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    RUBIDIUM
    37
    Rb
    85.4678 (3) g


    Name: rubidiumGroup number: 1
    Symbol: RbGroup name: Alkali metal
    Atomic number: 37Period number: 5
    Atomic weight: 85.4678 (3) gBlock: s-block
    CAS Registry ID: 7440-17-7Voice:
    Standard state: solid at 298 KColour: silvery white
    Classification: MetallicAvailability:

    rubidium
    Image adapted with permission from Prof James Marshall"s (U. North Texas, USA) Walking Tour of the elements CD.

    Rubidium can be liquid at ambient temperature, but only on a hot day given that its melting point is about 40°C. It is a soft, silvery-white metallic element of the alkali metals group (Group 1). It is one of the most most electropositive and alkaline elements. It ignites spontaneously in air and reacts violently with water, setting fire to the liberated hydrogen. As so with all the other alkali metals, it forms amalgams with mercury. It alloys with gold, caesium, sodium, and potassium. It colours a flame yellowish-violet.

    Nearing Zero cartoon for rubidium
    Nearing Zero cartoon included by kind permission of Nick Kim.

    Isolation

    Here is a brief summary of the isolation of rubidium.

    Rubidium would not normally be made in the laboratory as it is available commercially. All syntheses require an electrolytic step as it is so difficult to add an electron to the poorly electronegative rubidium ion Rb+.

    Rubidium is not made by the same method as sodium as might have been expected. This is because the rubidium metal, once formed by electrolysis of liquid rubidium chloride (RbCl), is too soluble in the molten salt.

    cathode: Rb+(l) + e- Rb (l)anode: Cl-(l) 1/2Cl2 (g) + e-

    Instead, it is made by the reaction of metallic sodium with hot molten rubidium chloride.

    Na + RbCl Rb + NaCl

    This is an equilibrium reaction and under these conditions the rubidium is highly volatile and removed from the system in a form relatively free from sodium impurities, allowing the reaction to proceed.

    Fluorides
  • RbF
  • Chlorides
  • RbCl
  • Bromides
  • RbBr
  • Iodides
  • RbI
  • Hydrides
  • HRb
  • Oxides
  • Rb2O
  • RbO2
  • Rb2O2
  • Sulfides
  • Rb2S
  • Selenides
  • Rb2Se
  • Tellurides
  • Rb2Te
  • Nitrides
    none listed






    Our data and resources are taken from Web Elements